Composition
Most plastics contain organic
polymers. The vast majority of these polymers are based on chains of carbon
atoms alone or with oxygen, sulfur, or nitrogen as well. The backbone is that
part of the chain on the main "path" linking a large number of repeat
units together. To customize the properties of a plastic, different molecular
groups "hang" from the backbone (usually they are "hung" as
part of the monomers before the monomers are linked together to form the
polymer chain). The structure of these "side chains" influence the
properties of the polymer. This fine tuning of the repeating unit's molecular
structure influences the properties of the polymer.
Most plastics contain other organic or inorganic compounds blended in.
The amount of additives ranges from zero percentage (for example in polymers
used to wrap foods) to more than 50% for certain electronic applications. The
average content of additives is 20% by weight of the polymer.
Many of the controversies associated with plastics are associated with
the additives. Organotin compounds are particularly toxic.
Fillers:
Fillers improve performance and/or reduce production costs. Stabilizing
additives include fire retardants to lower the flammability of the material.
Many plastics contain fillers, relatively inert and inexpensive materials that
make the product cheaper by weight.
Typically fillers are mineral in origin, e.g., chalk. Some fillers are
more chemically active and are called reinforcing agents. Other fillers include
zinc oxide, wood flour, ivory dust, cellulose and starch.
Plasticizers:
Since many organic polymers are too rigid for particular applications,
they are blended with plasticizers (the largest group of additives), oily
compounds that confer improved rheology.
Colorants
Colorants are common additives, although their weight contribution is
small.