Photovoltaics

A solar cell, or photovoltaic cell (PV), is a device that converts light into electric current using the photoelectric effect. This is based on the discovery by Alexandre-Edmond Becquerel who noticed that some materials release electrons when hit with rays of photons from light, which produces an electrical current. The first solar cell was constructed by Charles Fritts in the 1880s. Although the prototype selenium cells converted less than 1% of incident light into electricity, both Ernst Werner von Siemens and James Clerk Maxwell recognized the importance of this discovery. Following the work of Russell Ohl in the 1940s, researchers Gerald Pearson, Calvin Fuller and Daryl Chapin created the silicon solar cell in 1954. These early solar cells cost 286 USD/watt and reached efficiencies of 4.5–6%. As of late 2009, the highest efficieincy PV cells were produced commercially by Boeing/SpectroLab at about 41%. Other, similar, multi-layer cells are close. These are breathtakingly expensive however, and are used only for the most exacting applications. Thin film PV cells have been developed which are made in bulk and are far less expensive and much less fragile, but are at most around 20% efficient. The most recent development (from Caltech, March 2010) is the experimental demonstration of a new design which is 85% efficient in plain sunlight and 95% efficient at certain wavelengths. It has only been produced in experimental laboratory examples, but may have some possibility for low cost bulk production in future.

There are many competing technologies, including at least fourteen types of photovoltaic cells, such as thin film, monocrystalline silicon, polycrystalline silicon, and amorphous cells, as well as multiple types of concentrating solar power. It is too early to know which technology will become dominant.

The earliest significant application of solar cells was as a back-up power source to the Vanguard I satellite in 1958, which allow it to continue transmitting for over a year after its chemical battery was exhausted. The successful operation of solar cells on this mission was duplicated in many other Soviet and American satellites, and by the late 1960s, PV had become the established source of power for them. After the successful application of solar panels on the Vanguard satellite it still was not until the energy crisis, in the 1970s, that photovoltaic solar panels gained use outside of back up power suppliers on spacecraft. Photovoltaics went on to play an essential part in the success of early commercial satellites such as Telstar, and they remain vital to the telecommunications infrastructure today.

The high cost of solar cells limited terrestrial uses throughout the 1960s. This changed in the early 1970s when prices reached levels that made PV generation competitive in remote areas without grid access. Early terrestrial uses included powering telecommunication stations, offshore oil rigs, navigational buoys and railroad crossings. These off-grid applications accounted for over half of worldwide installed capacity until 2004.

The 1973 oil crisis stimulated a rapid rise in the production of PV during the 1970s and early 1980s. Economies of scale which resulted from increasing production along with improvements in system performance brought the price of PV down from 100 USD/watt in 1971 to 7 USD/watt in 1985. Steadily falling oil prices during the early 1980s led to a reduction in funding for photovoltaic R&D and a discontinuation of the tax credits associated with the Energy Tax Act of 1978. These factors moderated growth to approximately 15% per year from 1984 through 1996.

Since the mid-1990s, leadership in the PV sector has shifted from the US to Japan and Europe. Between 1992 and 1994 Japan increased R&D funding, established net metering guidelines, and introduced a subsidy program to encourage the installation of residential PV systems. As a result, PV installations in the country climbed from 31.2 MW in 1994 to 318 MW in 1999, and worldwide production growth increased to 30% in the late 1990s.

Germany became the leading PV market worldwide since revising its feed-in tariffs as part of the Renewable Energy Sources Act. Installed PV capacity in Germany has risen from 100 MW in 2000 to approximately 4,150 MW at the end of 2007. After 2007, Spain became the largest PV market after adopting a similar feed-in tariff structure in 2004, installing almost half of the photovoltaics (45%) in the world, in 2008, while France, Italy, South Korea and the U.S. have seen rapid growth recently due to various incentive programs and local market conditions. The power output of domestic photovoltaic devices is usually described in kilowatt-peak (kWp) units, as most are from 1 to 10 kW.

Concentrating photovoltaics (CVP) are another new method of electricity generation from the sun. CPV systems employ sunlight concentrated onto photovoltaic surfaces for the purpose of electrical power production. Solar concentrators of all varieties may be used, which are often mounted on a solar tracker in order to keep the focal point upon the cell as the sun moves across the sky. Tracking can increase flat panel photovoltaic output by 20% in winter, and by 50% in summer.