Combustion Air and Turbine
Exhaust Gas
Temperature and Composition
Oxygen used for supplementary
firing in HRSG co-generation applications is provided by the residual in the
turbine exhaust gas instead of from an external source of air. Because this
flue gas is already at an elevated temperature, duct burner thermal efficiency
can approach 100%, as relatively little heat is required to raise the
combustion product temperature to the final fired temperature entering the
boiler. TEG, however, contains less oxygen than fresh air, typically between 11
and 16% by volume, which in conjunction with the TEG temperature significantly
affects the combustion process. As the oxygen concentration and TEG temperature
decrease, products of incomplete combustion (CO and unburned hydrocarbons)
occur more readily, eventually progressing to combustion instability.
The effect of low oxygen
concentrations can be partially offset by higher temperature; and, conversely,
higher oxygen concentrations will partially offset the detrimental effects of
low TEG temperatures. This general relationship is shown in this figure.
The burner can then be
designed to create a localhightemperature condition
for stable combustion, while not allowing premature quenching by the remaining
excess TEG. Flame speed is another measure of combustibility and can be
calculated for unusual fuel constituents. The oxygen remaining from the turbine
combustion is usually many times greater than required for supplemental firing.
The final concentration of O2 after supplemental firing is frequently still
above 10%. In the extreme, a fully fired boiler is possible, with the residual
O2 as low as 2%. Fully fired HRSGs can produce large amounts of steam but are
rare because the economics favor the
power-to-heat ratio of unfired or supplemental fired HRSG.