Combustion Air
and Turbine Exhaust Gas
Temperature and
Composition
Oxygen used for
supplementary firing in HRSG co-generation applications is provided by the
residual in the turbine exhaust gas instead of from an external source of air.
Because this flue gas is already at an elevated temperature, duct burner
thermal efficiency can approach 100%, as relatively little heat is required to
raise the combustion product temperature to the final fired temperature
entering the boiler. TEG, however, contains less oxygen than fresh air,
typically between 11 and 16% by volume, which in conjunction with the TEG
temperature significantly affects the combustion process. As the oxygen
concentration and TEG temperature decrease, products of incomplete combustion
(CO and unburned hydrocarbons) occur more readily, eventually progressing to combustion
instability.
The effect of low
oxygen concentrations can be partially offset by higher temperature; and,
conversely, higher oxygen concentrations will partially offset the detrimental
effects of low TEG temperatures. This general relationship is shown in this
figure.
The burner can
then be designed to create a local high temperature condition
for stable combustion, while not allowing premature quenching by the remaining
excess TEG. Flame speed is another measure of combustibility and can be
calculated for unusual fuel constituents. The oxygen remaining from the turbine
combustion is usually many times greater than required for supplemental firing.
The final concentration of O2 after supplemental firing is frequently still
above 10%. In the extreme, a fully fired boiler is possible, with the residual
O2 as low as 2%. Fully fired HRSGs can produce large amounts of steam but are
rare because the economics favor the
power-to-heat ratio of unfired or supplemental fired HRSG.