Cement is a commonly
used binding material in the construction. The cement is obtained by burning a
mixture of calcareous (calcium) and argillaceous (clay) material at a very high
temperature and then grinding the clinker so produced to a fine powder. It was
first produced by a mason Joseph Aspdin in England
in 1924. He patented it as portland cement.
In addition to ordinary portland cement there are many varieties of cement.
Important varieties are briefly explained below:
The cement when made
free from colouring oxides of iron, maganese and chlorium results into white cement. In the manufacture
of this cement, the oil fuel is used instead of coal for burning. White cement is
used for the floor finishes, plastering, ornamental works etc. In swimming pools
white cement is used to replace glazed tiles. It is used for fixing marbles and
glazed tiles.
The cements of desired
colours are produced by intimately mixing pigments with ordinary cement.
The chlorium oxide gives green colour.
Cobalt produce blue colour.Iron oxide with
different proportion produce brown, red or yellow colour. Addition of manganese
dioxide gives black or brown coloured cement. These cements are used for giving
finishing touches to floors,walls,
window sills, roofs etc.
Quick setting cement
is produced by reducing the percentage of gypsum and adding a small amount of
aluminium sulphate during the manufacture of cement. Finer grinding also adds
to quick setting property. This cement starts setting within 5 minutes after
adding water and becomes hard mass within 30 minutes. This cement is used to
lay concrete under static or slowly running water.
This cement
can be produced by increasing lime content and burning at high temperature
while manufacturing cement. Grinding to very fine is also necessary. Though the
initial and final setting time of this cement is the same as that of portland cement, it gains strength in early days. This
property helps in earlier removal of form works and speed in construction
activity.
In mass concrete
works like construction of dams, heat produced due to hydration of cement will
not get dispersed easily. This may give rise to cracks. Hence in such
constructions it is preferable to use low heat cement. This cement contains low
percentage (5%) of tricalcium aluminate(C3A) and higher percentage (46%) of dicalcium silicate (C2S).
Pozzolana is a volcanic power found
in Italy. It can be processed from shales and certain types of clay also. In
this cement pozzolana material is 10 to 30
per cent. It can resist action of sulphate. It releases less heat during
setting. It imparts higher degree of water tightness. Its tensile strength is
high but compressive strength is low. It is used for mass concrete works. It is
also used in sewage line works.
This cement
expands as it sets. This property is achieved by adding expanding medium like sulpho aluminate and a stabilizing agent to ordinary
cement. This is used for filling the cracks in concrete structures.
It is manufactured
by calcining a mixture of lime and bauxite. It is more resistant to sulphate
and acid attack. It develops almost full strength within 24 hours of adding
water. It is used for underwater works.
(ix) Blast
Furnace Cement:
In the manufacture
of pig iron, slag comes out as a waste product. By grinding clinkers of cement
with about 60 to 65 per cent of slag, this cement is produced. The properties
of this cement are more or less same as ordinary cement, but it is cheap, since
it utilise waste product. This cement is durable but it gains the strength
slowly and hence needs longer period of curing.
This cement is produced
by adding acid resistant aggregated such as quartz, quartzite, sodium silicate
or soluble glass. This cement has good resistance to action of acid and water.
It is commonly used in the construction of chemical factories.
By keeping the
percentage of tricalcium aluminate C3A
below five per cent in ordinary cement this cement is produced. It is used in
the construction of structures which are likely to be damaged by alkaline conditions.
Examples of such structures are canals, culverts etc.
Fly ash is
a byproduct in thermal stations. The particles
of fly ash are very minute and they fly in the air, creating air pollution
problems. Thermal power stations have to spend lot of money to arrest fly ash
and dispose safely. It is found that one of the best way to dispose fly-ash is
to mix it with cement in controlled condition and derive some of the beneficial
effects on cement. Nowadays cement factories produce the fly ash in their own
thermal stations or borrow it from other thermal stations and further process
it to make it suitable to blend with cement. 20 to 30% fly ash is used for blending.Fly ash blended cements have superior quality
of resistance to weathering action. The ultimate strength gained is the same as
that with ordinary portland cement. However
strength gained in the initial stage is slow.